Chinese Physics C > 2005, Vol. 29 > Issue(S1): 89-92

Speciation of Elements in PM10 of Tunnel Studied by XAFS

中科院上海原子核研究所

Abstract
HTML
Reference
Related

PDF

Abstract：
The PM ₁₀samples were collected at three different sites in or out a tunnel in Shanghai. The XAFS (X-ray absorption fine structure) spectroscopy was applied for the speciation of iron and lead in the samples. The chemical components were determined by IFEFFIT program. The results show: Fe ₂O ₃, Fe ₃O ₄, Fe ₂(NO ₃) ₃and FeO are presented as the main components in the samples of different sites. In the middle of the tunnel, Fe(NO ₃) ₃and FeO are in high proportion, but outside of the tunnel, the proportion of these two components goes down, besides, the proportion of Fe ₂O ₃increases. The main lead species are PbSO ₄, PbO ₂, Pb ₃(PO ₄) ₂and a little PbO in samples of different sites. Similarly, the proportion of PbSO ₄and PbO ₂is higher than that of the outside. And there is a small amount of PbO out of the tunnel. There is considerable difference between the middle and outside in the two elemental species, which is caused by the different pollution source and environment.

References

[1]

. Huggins F E, Gerald P, Robertson J D. J. Hazardous Ma-terials, 2000, 74: 1—232. Kopcewicz B, Kopcewicz M. Struct. Chem, 1991,2:(95)303—(104)3123. YAO Xiao-Hong, Chak K. Chan, FANG Ming et al. Atmo-spheric Environment, 2002, 36: 4223—42344. Yule W, Lansdown R, Millar I B et al. Dev. Med. ChildNeuro, 1981, 23: 567—5765. LUO Kun-Li, WANG Dou-Hu, TAN Jian-An et al. Envi-ronmental Science, 2002, 23(1): 123—125(in Chinese)(雒昆利，王斗虎，谭见安等.环境科学，2002, 23(1): 123-125)6. US EPA Environmental Criteria and Assessment Office(1996)7. Pavageau M, P′echeyran C, Krupp E M et al. Environmen-tal Science and Technology, 2002, 36: 1561—15738. Ressler T, Wong J, Roos J et al. Environmental Scienceand Technology, 2000, 34: 950—9589. WANG Wei, YE Hui-Hai, JIN Da-Shan et al. Research ofEnvironmental Sciences, 2001, 4: 27—31(in Chinese)(王玮，叶慧海，金大善等.环境科学研究,2001, 4: 27-31)10. LI Ai-Guo, TONG Yong-Peng, NI Xin-Bo et al. China En-vironmental Science, 2001, 21(3): 198—202(in Chinese)(李爱国，童永彭，倪新伯等.中国环境科学，2001, 21(3):198-202)

[1]	Min Wu,Li-Rong Zheng,Sheng-Qi Chu,Ai-Yu Zhou,Jing Zhang,Tian-Dou Hu. A new technique to measure the differential XAFS spectrum. Chinese Physics C, 2016, 40(4): 048001.doi:10.1088/1674-1137/40/4/048001
[2]	WANG Jia-Ou,DU Yong-Hua,Kurash Ibrahim,HONG Cai-Hao,XIE Ya-Ning,HU Tian-Dou. Study on Perovskite Oxides LaFe_1－xCr_xO₃by EXAFS. Chinese Physics C, 2007, 31(1): 101-103.
[3]	CAO Yun,FENG Yu-Cheng,LI Jin-Yu,WANG Hui,MA Bao-Hua,SUN Liang-Ting,ZHAO HUAN-Yu,SHANG Yong,ZHANG Xue-Zhen,LI Xi-Xia,GUO Xiao-Hong,LU Wang. Research on Metallic Ion Beam Production at IMP. Chinese Physics C, 2007, 31(S1): 70-74.
[4]	JIN Xiao,LI Ming,XU Zhou,LI Wei-Hua,YANG Xing-Fan,CHEN Tian-Cai,XU Yong,YU Hong,WANG Yuan,SHEN Xu-Ming,CHENG Yun,XIE Min,LU He-Ping,DENG De-Rong,,,. Experiment research of CAEP FIR-FEL. Chinese Physics C, 2006, 30(S1): 96-98.
[5]	CHEN Dong-Liang,WU Zi-Yu,WEI Shi-Qiang. MS-XANES Studies on the Interface Effect of Semiconductor InSb Nanoparticles Embedded in a-SiO₂Matrix. Chinese Physics C, 2006, 30(5): 476-480.
[6]	HU Shu-Xin,LI Da-Peng,MAI Zhen-Hong,LI Ming. Small Angle X-ray Scattering Study of the Influence of Temperature on the Structure of DNA/Lipid Complexes. Chinese Physics C, 2005, 29(S1): 4-7.
[7]	WANG Jiang-Xue,CHEN Chun-Ying,SUN Jin,YU Hong-Wei,LI Yu-Feng,LI Bai,XING Li,HUANG Yu-Ying,HE Wei,GAO Yu-Xi,CHAI Zhi-Fang,ZHAO Yu-Liang. Translocation of Inhaled TiO2 Nanoparticles Along Olfactory Nervous System to Brain Studied by Synchrotron Radiation X-Ray Fluorescence. Chinese Physics C, 2005, 29(S1): 76-79.
[8]	YU Zong-Qiang,ZHOU Hua-Shi,GAO Shu-Qi. Coherent X-Ray Scatter for Identifiction of Explosives. Chinese Physics C, 2005, 29(6): 619-622.
[9]	WANG Bing,FENG Wei-Yue,WANG Meng,SHI Jun-Wen,ZHANG Fang,OUYANG Hong,ZHAO Yu-Liang,CHAI Zhi-Fang,HUANG Yu-Ying,XIE Ya-Ning. Microtranslocation of Trace Element in the Olfactory Bulb of Mice after Intranasal Instillation of Fine Oxide Particle by Synchrotron Radiation X-Ray Fluorescence. Chinese Physics C, 2005, 29(S1): 71-75.
[10]	LI Xiao-Lin,YUE Wei-Sheng,LIU Jiang-Feng,WAN Tian-Min,LI Yan,ZHANG Gui-Lin,YAN Cong-Huai,ZHANG Zhong-De,HUANG Yu-Ying,HE Wei. Study of Distribution and Correlation of Elements in Bone of the Rat Exposed to Lead by Synchrotron. Chinese Physics C, 2005, 29(S1): 65-67.
[11]	YU Wan-Li,LUO Yong-An,TIAN Yu-Lian,HUANG Wan-Xia,JIA Xiao-Peng. Study of the Dislocations in Large Synthesized Diamond Crystal with Synchrotron Radiation. Chinese Physics C, 2003, 27(S1): 92-96.
[12]	JIA Qing-Ying,BAN Yong,JI Xiao-Bin,ZOU Bing-Song. Effects of Simulation and Detection of Low-Momentum Final State Particles on the Research of Baryon Spectroscopy. Chinese Physics C, 2003, 27(12): 1053-1057.
[13]	CHU Wang-Sheng,HU Tian-Dou,XIE Ya-Ning,LIU Wen-Han,WU Zi-Yu,. Metal K-edge XAS Study of AlB2-type Transition-metal Diborides. Chinese Physics C, 2003, 27(S1): 10-14.
[14]	LIU Min-Liang,ZHANG Yu-Hu,LIU Zhong,ZHOU Xiao-Hong,GUO Ying-Xiang,LEI Xiang-Guo,HE Jian-Jun,ZHENG Yong,LUO Wan-Ju,ZHU Li-Hua,WEN Shu-Xian. In-beam γ-Ray Spectroscopy of Excited States in¹⁴¹Nd. Chinese Physics C, 2003, 27(5): 406-410.
[15]	XIAO Wan-Sheng,WENG Ke-Nan,XU Shi-Ping,CHEN Jin-Yang,HONG Shi-Ming,HAN Yin-Wen. Study on elemental mobility in the process of ultrahigh-pressure metamorphism by SRXRF. Chinese Physics C, 2003, 27(S1): 77-82.
[16]	HU Rong,LIU Jing,M.I.Abbas,HU Tian-Dou,Xie Ya-Ning,FENG Wei-Yue,CHAI Zhi-Fang,Wu Zi-Yu. XAFS Investigation of Chromium(Ⅲ)-Amino Acid-Nicotinic Acid Mixed Ligand Complexes. Chinese Physics C, 2003, 27(S1): 15-18.
[17]	XIE Ya-Ning,LUO Jun,TAO Ye,ZHANG Jing,HU Tian-Dou. New Development of XAFS Experimental Methods at BSRF. Chinese Physics C, 2001, 25(S1): 7-11.
[18]	Zhai Pengji,Feng Songlin,Zhang Ying,Tang Xiaowei,Liu Jie,Hou Mingdong,Liu Changlong,Wu Ji,Wang Chen,Shang Guangyi,Bai Chunli. Observation of the Damage on HOPG Surface Induced by Ar⁺⁸Ions. Chinese Physics C, 1999, 23(6): 579-583.
[19]	Jiang Haiyin,Wang Dewu,Liu Jianfei,Wu Zhonghua,Xie Yahing,Gu Mu,Chen Lingyan. Study of Fluorescent Decay Properties of Fluorides With Beijing Synchrotron Radiation Source. Chinese Physics C, 1996, 20(12): 1103-1109.
[20]	XU Fuxin,XU Ni. A Comprehensive Analysis for Eight Formulas for Rotational Spectra. Chinese Physics C, 1993, 17(11): 1040-1047.

Access

Get Citation

JIN Chan, ZOU Yang, ZHANG Gui-Lin, TAN Ming-Guang, PENG Lan, LI Yu-Lan, CHEN Wen-Zhong, LI Yan, XIE Ya-Ning and LIU Tao. Speciation of Elements in PM10 of Tunnel Studied by XAFS[J]. Chinese Physics C, 2005, 29(S1): 89-92.

RIS(for EndNote,Reference Manager,ProCite)

BibTex

Txt

Milestone

Received: 2005-10-28
Revised: 1900-01-01

Article Metric

Article Views(4464)
PDF Downloads(670)
Cited by(0)

Policy on re-use

To reuse of subscription content published by CPC, the users need to request permission from CPC, unless the content was published under an Open Access license which automatically permits that type of reuse.

通讯作者:陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Speciation of Elements in PM10 of Tunnel Studied by XAFS

Corresponding author:LI Yan,

中科院上海原子核研究所

Received Date:2005-10-28

Accepted Date:1900-01-01

Available Online:2005-01-02

Abstract:The PM₁₀samples were collected at three different sites in or out a tunnel in Shanghai. The XAFS (X-ray absorption fine structure) spectroscopy was applied for the speciation of iron and lead in the samples. The chemical components were determined by IFEFFIT program. The results show: Fe₂O₃, Fe₃O₄, Fe₂(NO₃)₃and FeO are presented as the main components in the samples of different sites. In the middle of the tunnel, Fe(NO₃)₃and FeO are in high proportion, but outside of the tunnel, the proportion of these two components goes down, besides, the proportion of Fe₂O₃increases. The main lead species are PbSO₄, PbO₂, Pb₃(PO₄)₂and a little PbO in samples of different sites. Similarly, the proportion of PbSO₄and PbO₂is higher than that of the outside. And there is a small amount of PbO out of the tunnel. There is considerable difference between the middle and outside in the two elemental species, which is caused by the different pollution source and environment.

HTML

Reference (1)

Speciation of Elements in PM10 of Tunnel Studied by XAFS

Abstract：

References

Access

Article Metrics

Metrics

通讯作者:陈斌, bchen63@163.com

Email This Article