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Removal of hydrogen sulfide in carbon dioxide for radiocarbon AMS analysis

SPT-2
24 Oct 2024, 09:40
20m
GRAND BALLROOM (宴会厅), 2nd Floor

GRAND BALLROOM (宴会厅), 2nd Floor

GULIN BRAVO HOTEL (桂林宾馆),14 Ronghu Road, Guilin, 541002, China
Oral Presentation Sample Preparation Techniques Sample Preparation Techniques

Speaker

DrMark Roberts(Woods Hole Oceanographic Institution)

Description

A method of hydrogen sulfide removal in water (for DIC radiocarbon analysis) or carbon dioxide gas was investigated. By using a silver nitrate solution in diluted nitric acid in a gas wash device, or a trap filled with silver nitrate impregnated silica gel, the hydrogen sulfide was easily removed from the carbon dioxide. The cleaned CO2 is pure enough to get reduced by hydrogen on the iron catalyst for graphite AMS measurement. The blank of this clean-up method is negligible. It will not change the isotopic composition of the CO2. This method is applied to some hydrogen sulfide containing samples successfully.

Student Submission No

Primary author

DrLi Xu(Woods Hole Oceanographic Institution)

Co-authors

MrAlan Gagnon DrMark Roberts(Woods Hole Oceanographic Institution) DrRoberta Hansman(Woods Hole Oceanographic Institution) MrsKathern Elder(Woods Hole Oceanographic Institution) DrJeffrey Seewald(Woods Hole Oceanographic Institution) DrSusan Lang(Woods Hole Oceanographic Institution)

Presentation materials

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